Low pressure ethenolysis of renewable methyl oleate in a microchemical system
- 등재 SCIE, SCOPUS
- 발행기관 American Chemical Society
- 발행년도 2011
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000092212
- 본문언어 영어
- Published As http://dx.doi.org/10.1021/ol200634y
초록/요약
Chemical equations presented. A microchemical system for ethenolysis of renewable methyl oleate was developed, in which the dual-phase, microfluidic design enabled efficient diffusion of ethylene gas into liquid methyl oleate through an increased contact area. The increased mass transfer of ethylene favored the formation of desired commodity chemicals with significantly suppressed homometathesis when compared to the bulk system. In addition to higher selectivity and conversion, this system also provides the typical advantages of a microchemical system, including the possibility of convenient scale-up. © 2011 American Chemical Society.
more