An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion
- 등재 SCIE, SCOPUS
- 발행기관 ROYAL SOC CHEMISTRY
- 발행년도 2014
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000086925
- 본문언어 영어
- Published As http://dx.doi.org/10.1039/c3cc48782b
초록/요약
Reaction of a nonheme iron(III)-peroxo complex, [Fe-III(14-TMC)(O-2)](+), with NO+, a transformation which is essentially isoelectronic with that for nitric oxide dioxygenases [Fe(III)(O-2(center dot-)) + NO], affords an iron(IV)-oxo complex, [Fe-IV(14-TMC)(O)](2+), and nitrogen dioxide (NO2), followed by conversion to an iron(III)-nitrato complex, [Fe-III(14-TMC)(NO3)(F)](+).
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