Mechanistic insight into the hydroxylation of alkanes by a nonheme iron(V)-oxo complex
- 등재 SCIE, SCOPUS
- 발행기관 ROYAL SOC CHEMISTRY
- 발행년도 2014
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000091330
- 본문언어 영어
- Published As http://dx.doi.org/10.1039/c4cc01058b
초록/요약
Hydroxylation of alkanes by a mononuclear nonheme iron(V)-oxo complex, [Fe(V)(O)(TAML)](-), is initiated by a rate-determining hydrogen atom(H-atom) abstraction, followed by an oxygen non-rebound process. Evidence for the H-atom abstraction-oxygen non-rebound mechanism is obtained experimentally and supported by DFT calculations.
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