DMF as a Source of Oxygen and Aminomethine : Stereoselective 1,2-Insertion of Rhodium(II) Azavinyl Carbenes into the C=O Bond of Formamides for the Synthesis of cis-Diamino Enones
- 등재 SCIE, SCOPUS
- 발행기관 AMER CHEMICAL SOC
- 발행년도 2014
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000091362
- 본문언어 영어
- Published As http://dx.doi.org/10.1021/ol500723s
초록/요약
A new catalytic reaction in which all the atoms of a formamide are incorporated into the product through a formal stereoselective 1,2-insertion of rhodium(II) azavinyl carbenes, generated in situ from readily available N-sulfonylated 1,2,3-triazoles, into the C=O bond of DMF and other N,N-disubstituted formamides to afford cis-diamino enones is described.
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