Hydride transfer from NADH analogues to a nonheme manganese(IV)-oxo complex via rate-determining electron transfer
- 등재 SCIE, SCOPUS
- 발행기관 ROYAL SOC CHEMISTRY
- 발행년도 2014
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000109751
- 본문언어 영어
- Published As http://dx.doi.org/10.1039/c4cc05313c
초록/요약
Hydride transfer from NADH analogues to a nonheme Mn(IV)-oxo complex, [(Bn-TPEN) Mn-IV(O)](2+), proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 +/- 0.1); a charge-transfer complex formed between the MnIV(O) complex and NADH analogues is involved in the hydride transfer reaction.
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