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Mononuclear nonheme iron(IV)-oxo and manganese(IV)-oxo complexes in oxidation reactions: Experimental results prove theoretical prediction

초록/요약

Reactivities of mononuclear nonheme iron(iv)-oxo and manganese(iv)-oxo complexes bearing a pentadentate N4Py ligand, [MIVO(N4Py)]2+ (M = Fe and Mn), are compared in hydrogen atom transfer (HAT) and oxygen atom transfer (OAT) reactions; theoretical and exp

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