Existence of nanoparticles in azurite and malachite pigments – Raman spectroscopy and X-ray diffraction studies
- 주제(키워드) Mineral pigment , Nanoparticles , Nondestructive measurements , Raman spectroscopy , X-ray diffraction
- 등재 SCIE, SCOPUS
- 발행기관 Elsevier Ltd
- 발행년도 2016
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000135018
- 본문언어 영어
- Published As http://dx.doi.org/10.1016/j.dyepig.2016.06.004
- 저작권 이화여자대학교 논문은 저작권에 의해 보호받습니다.
초록/요약
The lightness of the color of mineral pigments changes with its particle size. We investigated the Raman spectra of azurite pigments of several particle-size groups, ranging from ∼5 to ∼110 μm. The line-widths of the phonon modes ∼400 cm−1 of azurite powders were found to increase as the particle sizes get smaller. Similar phenomena were also observed for the malachite pigments. The broadening of phonon modes implies the existence of nanoparticles in the pigment powder. Scanning Electron Microscopy (SEM) measurements confirm the existence of more nanoparticles in the finer particle-size groups. These results were assured by X-ray diffraction (XRD) measurements as well. Even further, we could determine the average size of azurite particles simply by comparing the line-width of the Raman mode ∼400 cm−1 of the unknown with that of the known particle-size groups. Non-destructive estimation of typical sizes of mineral pigments using Raman spectroscopy could be useful in cultural-heritage conservation science. © 2016 Elsevier Ltd
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