Intermetal oxygen atom transfer from an (FeO)-O-V complex to a Mn-III complex: an experimental and theoretical approach
- 등재 SCIE, SCOPUS
- 발행기관 ROYAL SOC CHEMISTRY
- 발행년도 2016
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000139834
- 본문언어 영어
- Published As http://dx.doi.org/10.1039/c6cc07152j
초록/요약
Oxygen atom transfer (OAT) reaction between an (FeO)-O-V complex and a Mn-III complex resulted in the eventual formation of their corresponding Fe-III and (MnO)-O-V complexes. The reaction proceeded via an initial fast OAT reaction between the (FeO)-O-V and Mn-III complexes, yielding a half equivalent of a (MnO)-O-V complex and a mu-oxo bridged Fe-IV dimer. The dimer regenerated the (FeO)-O-V species via equilibrium, which then reacted with the remaining Mn-III complex to produce another half equivalent of the (MnO)-O-V complex.
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