Autocatalytic dioxygen activation to produce an iron(V)-oxo complex without any reductants
- 등재 SCIE, SCOPUS
- 발행기관 ROYAL SOC CHEMISTRY
- 발행년도 2017
- URI http://www.dcollection.net/handler/ewha/000000147162
- 본문언어 영어
- Published As http://dx.doi.org/10.1039/c7cc03742b
초록/요약
An iron(V)-oxo complex with a tetraamido macrocyclic ligand, [(TAML)Fe-V(O)](-), was produced by reacting [(TAML)Fe-III](-) with dioxygen without any electron source in acetone at 298 K. The autocatalytic mechanism of dioxygen activation for the formation of an iron(V)-oxo complex has been clarified based on the autocatalysis by radical chain initiators.
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