A mononuclear manganese(III)-hydroperoxo complex: synthesis by activating dioxygen and reactivity in electrophilic and nucleophilic reactions
- 주제(기타) Chemistry, Multidisciplinary
- 등재 SCIE, SCOPUS
- 발행기관 ROYAL SOC CHEMISTRY
- 발행년도 2018
- URI http://www.dcollection.net/handler/ewha/000000149476
- 본문언어 영어
- Published As http://dx.doi.org/10.1039/c7cc09492b
초록/요약
We report the synthesis of manganese(III)-peroxo (Mn-III(O-2)) and manganese(III)-hydroperoxo (Mn-III(O2H)) complexes by activating dioxygen (O-2) and the amphoteric reactivity of the Mn(III)-hydroperoxo complex in electrophilic and nucleophilic reactions.
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