Synthesis and catalytic activity of electrospun NiO/NiCo2O4 nanotubes for CO and acetaldehyde oxidation
- 주제(키워드) electrospinning , bimetallic nanotubes , nickel , cobalt , catalytic oxidation
- 주제(기타) Nanoscience & Nanotechnology; Materials Science, Multidisciplinary; Physics, Applied
- 설명문(일반) [Kim, Il Hee; Jeong, Jae Hwan; Kim, Young Dok] Sungkyunkwan Univ, Dept Chem, Suwon 16419, South Korea; [Lee, Hyerim; Yu, Areum; Lee, Youngmi; Kim, Myung Hwa; Lee, Chongmok] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea
- 등재 SCIE, SCOPUS
- 발행기관 IOP PUBLISHING LTD
- 발행년도 2018
- URI http://www.dcollection.net/handler/ewha/000000151685
- 본문언어 영어
- Published As http://dx.doi.org/10.1088/1361-6528/aaaf12
초록/요약
NiO/NiCo2O4 nanotubes with a diameter of approximately 100 nm are synthesized using Ni and Co precursors via electro-spinning and subsequent calcination processes. The tubular structure is confirmed via transmission electron microscopy imaging, whereas the structures and elemental compositions of the nanotubes are determined using x-ray diffraction, energy dispersive x-ray spectroscopy, and x-ray photoelectron spectroscopy. N-2 adsorption isotherm data reveal that the surface of the nanotubes consists of micropores, thereby resulting in a significantly higher surface area (similar to 20 m(2) g(-1)) than expected for a flat-surface structure (<15 m(2) g(-1)). Herein, we present a study of the catalytic activity of our novel NiO/NiCo2O4 nanotubes for CO and acetaldehyde oxidation. The catalytic activity of NiO/NiCo2O4 is superior to Pt below 100 degrees C for CO oxidation. For acetaldehyde oxidation, the total oxidation activity of NiO/NiCo2O4 for acetaldehyde is comparable with that of Pt. Coexistence of many under-coordinated Co and Ni active sites in our structure is suggested be related to the high catalytic activity. It is suggested that our novel NiO/NiCo2O4 tubular structures with surface microporosity can be of interest for a variety of applications, including the catalytic oxidation of harmful gases.
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