A Mononuclear Nonheme Iron(IV)-Amido Complex Relevant for the Compound II Chemistry of Cytochrome P450
- 등재 SCIE, SCOPUS
- OA유형 Green Submitted, Green Accepted
- 발행기관 American Chemical Society
- 발행년도 2019
- URI http://www.dcollection.net/handler/ewha/000000155662
- 본문언어 영어
- Published As http://dx.doi.org/10.1021/jacs.8b11045
- PubMed https://pubmed.ncbi.nlm.nih.gov/30558411
- 저작권 이화여자대학교 논문은 저작권에 의해 보호받습니다.
초록/요약
A mononuclear nonheme iron(IV)-amido complex bearing a tetraamido macrocyclic ligand, [(TAML)FeIV(NHTs)]- (1), was synthesized via a hydrogen atom (H atom) abstraction reaction of an iron(V)-imido complex, [(TAML)FeV(NTs)]- (2), and fully characterized using various spectroscopies. We then investigated (1) the pKa of 1, (2) the reaction of 1 with a carbon-centered radical, and (3) the H atom abstraction reaction of 1. To the best of our knowledge, the present study reports for the first time the synthesis and chemical properties/reactions of a high-valent iron(IV)-amido complex. © 2018 American Chemical Society.
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