Pyrene-based bisboronic sensors for multichannel enantioselective recognition of tartaric acid
- 등재 SCIE, SCOPUS
- 발행기관 Elsevier Ltd
- 발행년도 2019
- URI http://www.dcollection.net/handler/ewha/000000155995
- 본문언어 영어
- Published As http://dx.doi.org/10.1016/j.dyepig.2018.11.059
- 저작권 이화여자대학교 논문은 저작권에 의해 보호받습니다.
초록/요약
New chiral bisboronic receptors based on pyrene-excimer were synthesized and applied for the determination of absolute configuration and enantiomeric composition of tartaric acid. The distinction was visualized by portable UV lamp in certain concentration range. There were three ways for the sensors to enantioselectively recognize tartaric acid, including the fluorescence spectrum, UV–vis spectrum, and CD spectrum. The enantiomeric excess of tartaric acid was measured quantitatively by using fluorescence analytical technique. Compared with the previous chiral boronic acid sensors, sensor 1 showed weaker background fluorescence and excellent chiral recognition ability of D/L-tartaric acid throughout the whole pH range. © 2018 Elsevier Ltd
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