Blue Electrofluorescence Resulting from Exergonic Harvesting of Triplet Excitons
- 주제(키워드) El-Sayed rule , electroluminescence , exciton harvest , fluorescent molecules , intersystem crossing
- 주제(기타) Materials Science, Multidisciplinary
- 주제(기타) Optics
- 관리정보기술 faculty
- 등재 SCIE, SCOPUS
- 발행기관 WILEY-V C H VERLAG GMBH
- 발행년도 2019
- URI http://www.dcollection.net/handler/ewha/000000161554
- 본문언어 영어
- Published As http://dx.doi.org/10.1002/adom.201900630
초록/요약
Advances in electroluminescence demand the development of emissive molecules capable of utilizing all of the electrogenerated excitons. Here, a molecular strategy to harvest the excitons without relying on late transition metals or thermal activation is designed and evaluated. The key process deployed is an exergonic, El-Sayed rule-allowed reverse intersystem crossing (ES-rISC) from the triplet n-pi * transition state to the singlet pi-pi * transition state, followed by fluorescent decay of the latter. To demonstrate the strategy, a series of fluorescent molecules consisting of a 9,10-diphenylanthracene core and different carbonyl n-pi * units (SY compounds) is created. The compounds display a strong blue fluorescence emission with high photoluminescence quantum yields of up to 0.93. Multilayer organic electroluminescence devices containing the SY compounds exhibit maximum external quantum efficiencies greater than that obtained from a singlet-exciton-only control device. This improvement is due to their capacity to utilize triplet excitons for fluorescence emission. The studies demonstrate that exergonic ES-rISC can serve as a promising pathway for creating inexpensive and tractable organic dopants for high-efficiency electroluminescence.
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