Visible-Light-Induced Trifluoromethylation of Unactivated Alkenes with Tri(9-anthryl)borane as an Organophotocatalyst
- 관리정보기술 faculty
- 등재 SCIE, SCOPUS
- 발행기관 American Chemical Society
- 발행년도 2019
- URI http://www.dcollection.net/handler/ewha/000000162364
- 본문언어 영어
- Published As http://dx.doi.org/10.1021/acs.joc.9b01624
- PubMed https://pubmed.ncbi.nlm.nih.gov/31389697
초록/요약
Tri(9-anthryl)borane was successfully applied as an organophotocatalyst for the visible-light-induced trifluoromethylation of unactivated alkenes with CF3I. The mild reaction conditions tolerated a variety of functional groups, and the reaction could be extended to perfluoroalkylations with C3F7I and C4F9I. Mechanistic studies revealed that the photoredox catalysis involves an oxidative quenching pathway. © 2019 American Chemical Society.
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