Structure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene Complex
- 주제(키워드) aldehyde deformylation reaction , amphoteric reactivity , cobalt(III) complexes , iodosylbenzene adducts , nonheme complexes
- 등재 SCIE, SCOPUS
- OA유형 Green Published
- 발행기관 Wiley-VCH Verlag
- 발행년도 2020
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000169488
- 본문언어 영어
- Published As https://dx.doi.org/10.1002/anie.202005091
- PubMed https://pubmed.ncbi.nlm.nih.gov/32358999
- 저작권 이화여자대학교 논문은 저작권에 의해 보호받습니다.
초록/요약
A mononuclear nonheme cobalt(III) iodosylbenzene complex, [CoIII(TQA)(OIPh)(OH)]2+ (1), is synthesized and characterized structurally and spectroscopically. While 1 is a sluggish oxidant in oxidation reactions, it becomes a competent oxidant in oxygen atom transfer reactions, such as olefin epoxidation, in the presence of a small amount of proton. More interestingly, 1 shows a nucleophilic reactivity in aldehyde deformylation reaction, demonstrating that 1 has an amphoteric reactivity. Another interesting observation is that 1 can be used as an oxygen atom donor in the generation of high-valent metal-oxo complexes. To our knowledge, we present the first crystal structure of a CoIII iodosylbenzene complex and the unprecedented reactivity of metal-iodosylarene adduct. © 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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