Proton-promoted disproportionation of iron(v)-imido TAML to iron(v)-imido TAML cation radical and iron(iv) TAML
- 주제(기타) Chemistry, Multidisciplinary
- 설명문(일반) [Lu, Xiaoyan; Lee, Yong-Min; Seo, Mi Sook; Nam, Wonwoo] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea
- 등재 SCIE, SCOPUS
- 발행기관 ROYAL SOC CHEMISTRY
- 발행년도 2020
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000174557
- 본문언어 영어
- Published As http://dx.doi.org/10.1039/d0cc05145d
- PubMed https://pubmed.ncbi.nlm.nih.gov/32820754
초록/요약
The present study reports the first example of a proton-promoted disproportionation reaction of a non-heme iron(v)-imido TAML (1) complex to give an iron(v)-imido TAML cation radical (2) and an iron(iv) TAML (3) upon addition of acids. Detailed mechanistic investigations revealed that two molecules of1react with one proton to yield2and [Fe-IV(NHTs)(TAML)](-)(4), followed by the reaction of4with another proton to afford3and NH2Ts.
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