Synergistic Dual Transition Metal Catalysis
- 주제(기타) Chemistry, Multidisciplinary
- 설명문(일반) [Kim, U. Bin; Jung, Da Jung; Jeon, Hyun Ji; Rathwell, Kris; Lee, Sang-gi] Ewha Womans Univ, Dept Chem, Seoul 120750, South Korea; [Kim, U. Bin; Jung, Da Jung; Jeon, Hyun Ji; Rathwell, Kris; Lee, Sang-gi] Ewha Womans Univ, Nanosci BK 21 Plus, Seoul 120750, South Korea
- 등재 SCIE, SCOPUS
- 발행기관 AMER CHEMICAL SOC
- 발행년도 2020
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000175398
- 본문언어 영어
- Published As http://dx.doi.org/10.1021/acs.chemrev.0c00245
- PubMed https://pubmed.ncbi.nlm.nih.gov/33251788
초록/요약
Synergistic catalysis, a type of plural catalysis which utilizes at least two different catalysts to enable a reaction between two separately activated substrates, has unlocked a plethora of previously unattainable transformations and novel chemical reactivity. Despite the appreciable utility of synergistic catalysis, specific examples involving two transition metals have been limited, as ensuring a judicious choice of reaction parameters to prevent deactivation of catalysts, undesirable monocatalytic event(s) leading to side products, or premature termination and other potentially troublesome outcomes present a formidable challenge. Excluding those driven by photocatalytic mechanisms, this review will highlight the reported examples of reactions that make use of two simultaneous catalytic cycles driven by two transition metal catalysts.
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