Acid Catalysis via Acid-Promoted Electron Transfer
- 주제(키워드) Metal‐ , oxygen complexes , Acid catalysis , Acid‐ , promoted electron transfer , Proton‐ , coupled electron transfer , Redox reaction
- 주제(기타) Chemistry, Multidisciplinary
- 설명문(일반) [Fukuzumi, Shunichi; Lee, Yong-Min; Nam, Wonwoo] Ewha Womans Univ, Dept Chem & Nano Sci, Seoul 03760, South Korea; [Fukuzumi, Shunichi] Meijo Univ, Fac Sci & Engn, Nagoya, Aichi 4680073, Japan; [Lee, Yong-Min] Ewha Womans Univ, Res Inst Basic Sci, Seoul 03760, South Korea
- 등재 SCIE, SCOPUS, KCI등재
- 발행기관 WILEY-V C H VERLAG GMBH
- 발행년도 2020
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000175777
- 본문언어 영어
- Published As http://dx.doi.org/10.1002/bkcs.12124
초록/요약
This feature article focuses on acid catalysis in various redox reactions of not only organic compounds but also metal complexes, in particular metal-oxygen complexes via acid-promoted electron transfer (APET). On the other hand, proton-coupled electron transfer (PCET) has been extensively studied in relation with important biological PCET reactions such as O-2 reduction in respiration and water oxidation in photosynthesis. Because PCET is normally defined as simultaneous electron and proton transfer from the same substrate, acid-promoted electron transfer using external acids is called APET in this article. Various types of chemical transformations exhibiting acid catalysis via APET discussed in this article include C-C bond formation, C-H bond oxidation, aromatic hydroxylation, and oxygen atom transfer reactions such as sulfoxidation and epoxidation reactions.
more