Reductive Electrophotocatalysis: Merging Electricity and Light To Achieve Extreme Reduction Potentials
- 주제(기타) Chemistry, Multidisciplinary
- 설명문(일반) [Kim, Hyunwoo; Lambert, Tristan H.; Lin, Song] Cornell Univ, Dept Chem & Chem Biol, Ithaca, NY 14853 USA; [Kim, Hyungjun] Incheon Natl Univ, Dept Chem, 119 Acad Ro, Incheon 22012, South Korea
- 등재 SCIE, SCOPUS
- 발행기관 AMER CHEMICAL SOC
- 발행년도 2020
- 총서유형 Journal
- URI http://www.dcollection.net/handler/ewha/000000182469
- 본문언어 영어
- Published As http://dx.doi.org/10.1021/jacs.9b10678
초록/요약
We describe a new electrophotocatalytic strategy that harnesses the power of light and electricity to generate an excited radical anion with a reducing potential of -3.2 V vs SCE, which can be used to activate substrates with very high reduction potentials (E-red approximate to -1.9 to -2.9 V). The resultant aryl radicals can be engaged in various synthetically useful transformations to furnish arylboronate, arylstannane, and biaryl products.
more