Green-Light-Driven Fe(III)(btz)3Photocatalysis in the Radical Cationic [4+2] Cycloaddition Reaction
- 관리정보기술 faculty
- 등재 SCIE, SCOPUS
- 발행기관 American Chemical Society
- 발행년도 2022
- URI http://www.dcollection.net/handler/ewha/000000193292
- 본문언어 영어
- Published As https://doi.org/10.1021/acs.orglett.2c01779
- PubMed https://pubmed.ncbi.nlm.nih.gov/35687841
초록/요약
Green-light-driven FeIII(btz)3photocatalysis for the radical cationic [4+2] cycloaddition of terminal styrenes and nucleophilic dienes has been investigated. The Fe-MIC (mesoionic carbene) complex forms a ligand-to-metal charge-transfer transition state with relatively high excited-state reduction potentials that can selectively oxidize terminal styrene derivatives. Unique multisubstituted cyclohexenes and structurally complex biorelevant cyclohexenes were constructed, highlighting the usefulness of this mild and practical first-row transition metal complex system. © 2022 American Chemical Society. All rights reserved.
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